Celesal DL [PDF]

Citation preview

SAFETY DATA SHEET According to Regulation (EC) N. 1907/2006



__________________________________________________________________________________________________________ 1 - PRODUCT AND COMPANY IDENTIFICATION __________________________________________________________________________________________________________ Commercial name CELESAL DL



02090000



Use of the substance/preparation Products for leather industry Company Cromogenia Units, S.A. Farell, 9 08014 Barcelona Emergency Telephone (93) 264.34.50 (93) 432.94.00 (93) 264.37.00 Instituto Nacional de Toxicologia: (91) 562.04.20 __________________________________________________________________________________________________________ 2 - HAZARDS IDENTIFICATION __________________________________________________________________________________________________________ Personal hazards Harmful if swallowed Irritating to skin Strong irritating to eyes Environment hazards None known __________________________________________________________________________________________________________ 3 - COMPOSITION/ INFORMATION ON COMPONENTS __________________________________________________________________________________________________________ Chemical composition Ethoxylated fatty alcohol Component ETHOXYLATED FATTY ALCOHOL



NºEINECS



CAS Nº



Concentration 80% - 90%



Classification Xn , Xi



Risk Phrases R22 R38 R41



The list of all mentioned R phrases (full text) is given under heading 16 __________________________________________________________________________________________________________ 4 - FIRST AID __________________________________________________________________________________________________________ Skin contact - Symptoms/Effects Irritation First aid Wash the affected area with plenty of water and soap Seek medical attention if the irritation persists Eye contact - Symptoms/Effects Severe irritation, redness, tears First aid Immediately wash out with plenty of water, holding the eyelids apart, for at least 15 minutes __________________________________________________________________________________________________________ DHS0802 02090000 CELESAL DL Revision 3 Issue 28 May 2007



-Page 1 of 5



SAFETY DATA SHEET According to Regulation (EC) N. 1907/2006



Seek medical attention Inhalation - Symptoms/Effects First aid The product is not volatile: but if in some situations, e.g. in a fire, fumes are inhaled, remove the injured person from exposure to air Seek medical attention Ingestion



- Symptoms/Effects Data not available First aid Rinse the mouth and go immediately to hospital __________________________________________________________________________________________________________ 5 - FIRE FIGHTING MEASURES __________________________________________________________________________________________________________ Extinguishing media Carbon dioxide, dry powder, foam Protective equipment A self contained breathing apparatus (SCBA) with visor covering face or equivalent Fire hazards May generate toxic components Do NOT use __________________________________________________________________________________________________________ 6 - ACCIDENTAL SPILLAGE MEASURES __________________________________________________________________________________________________________ Personal Avoid contact with the spilled liquid Environment Stop the leak if does not involve any risk Prevent the liquid entering sewers, watercourses, pits or ditches Cleaning up methods Use earth or sand to prevent the spillage from spreading Absorb the rest with suitable inert material ( earth, sand ... ) Move the product into a safe dry container and take it to a suitable place __________________________________________________________________________________________________________ 7 - HANDLING AND STORAGE __________________________________________________________________________________________________________ Handling Do not eat or drink while the product is being handled Wash hands before any break and at the end of the work Avoid eye and skin contact Storage Keep the container tightly closed __________________________________________________________________________________________________________ 8 - EXPOSURE CONTROL/PERSONAL PROTECTION __________________________________________________________________________________________________________ __________________________________________________________________________________________________________ DHS0802 02090000 CELESAL DL Revision 3 Issue 28 May 2007



-Page 2 of 5



SAFETY DATA SHEET According to Regulation (EC) N. 1907/2006



Technical measures See information in preceding paragraph Limit values Biological standards Respiratory protection Respirator with filter for organic vapours Skin protection Use rubber gloves Eye protection Use goggles for protection against splashes __________________________________________________________________________________________________________ 9 - PHYSICAL AND CHEMICAL PROPERTIES __________________________________________________________________________________________________________ Appearance



Transparent colourless liquid



Odour



Characteristic



pH



6-8



( 10 g/l water )



Density Viscosity



< 100 mPa.s



Solubility



In water ( 45ºC ) : 200 g/l. In IPA ( 20ºC ) : soluble



Boiling point Melting point



-8ºC / -3ºC



Flash point



n.a.



Others __________________________________________________________________________________________________________ 10 - STABILITY AND REACTIVITY __________________________________________________________________________________________________________ Hazardous reactions Nothing in special Conditions to avoid Do not heat over 100ºC, it contains water Materials to avoid Strong oxidants Hazardous decomposition products May generate ethylene oxide adducts __________________________________________________________________________________________________________ 11 - TOXICOLOGICAL INFORMATION __________________________________________________________________________________________________________ DHS0802 02090000 CELESAL DL Revision 3 Issue 28 May 2007



-Page 3 of 5



SAFETY DATA SHEET According to Regulation (EC) N. 1907/2006



__________________________________________________________________________________________________________ Acute toxicity Irritating to skin and risk of serious damage to the eyes 500 mg/kg< LD50 (oral, rat ) < 2000 mg/kg Harmful if swallowed Chronic effects None known __________________________________________________________________________________________________________ 12 - ECOLOGICAL INFORMATION __________________________________________________________________________________________________________ Mobility The product is soluble in water and can be transported considerable distances if allowed to enter watercourses Degradation Readily biodegradable Aquatic toxicity Others __________________________________________________________________________________________________________ 13 - DISPOSAL __________________________________________________________________________________________________________ Incinerate in accordance with local or governmental regulations __________________________________________________________________________________________________________ 14 - TRANSPORT __________________________________________________________________________________________________________ UN



Not classified as hazardous for transport CLASS



ADR/RID: IATA: IMDG:



PACKING GROUP



LABEL



Cod: Em-S:



__________________________________________________________________________________________________________ 15 - REGULATORY INFORMATION __________________________________________________________________________________________________________ Hazard symbol Xn Risk phrases R22 Harmful if swallowed. R38 Irritating to skin. R41 Risk of serious damage to eyes. Safety phrases S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37/39 Wear suitable gloves and eye/face protection. __________________________________________________________________________________________________________ DHS0802 02090000 CELESAL DL Revision 3 Issue 28 May 2007



-Page 4 of 5



SAFETY DATA SHEET According to Regulation (EC) N. 1907/2006



S46 Contains :



If swallowed, seek medical advice immediately and show this container or label.



Ethoxylated fatty alcohol Remarks __________________________________________________________________________________________________________ 16 - OTHER INFORMATION __________________________________________________________________________________________________________ This product, in spite of the fact that it is classified as Xn for HANDLING ( LD50 (oral,rat) < 2000mg/kg ), is not considered as hazardous by the transport regulations (ADR, IMDG, IATA) because its LD50 ( oral, rat ) > 300 mg/kg ( limit for a material to belong to the 6.1 class in the ADR, IMDG, IATA ) This Material Safety Data Sheet modifies, in relation to the previous version, the following paragraphs : 1,2,16 This Material Safety Data Sheet has been compiled in accordance with : - EC Directive 1999/45/EC and subsequent amendments, about 'Classification, Packaging and Labelling of Hazardous Goods' - Regulation (EC) No 1907/2006 - European Agreement concerning the International Carriage of Dangerous Goods by Road ( ADR ) - Technical Instructions for the Safe Transport of Dangerous Goods by Air ( IATA ) - International Maritime Dangerous Goods Code ( IMDG Code ) R prhases (full text) R22 Harmful if swallowed. R38 Irritating to skin. R41 Risk of serious damage to eyes. __________________________________________________________________________________________________________ The above information is based on the present state of our knowledge and experience and given in good faith. Users are advised of possible additional hazards when the product is used in applications for which it was not intended.



__________________________________________________________________________________________________________ DHS0802 02090000 CELESAL DL Revision 3 Issue 28 May 2007



-Page 5 of 5