GAA MSDS Rev.03.3 [PDF]

Citation preview

PT. NIPPON SHOKUBAI INDONESIA KAWASAN INDUSTRI PANCAPURI JL. RAYA ANYER KM 122 CIWANDAN, CILEGON 42447 BANTEN, INDONESIA TEL :(62-254)600660 (HUNTING), FAX :(62-254)600657, 600658



M S D S No. 002 – NSI – 1998 (SDS-Acrylic Acid) DATE PREPARED DATE REVISED



Page 1 of 9 : 1st SEPTEMBER 1998 : 10th JULY 2008



SAFETY DATA SHEET 1. PRODUCT AND COMPANY IDENTIFICATION



 CHEMICAL PRODUCT NAME :



GLACIAL ACRYLIC ACID



 



COMPANY NAME ADDRESS



: :



  



TEL NO. FAX NO. EMERGENCY TEL NO.



: : :



PT. NIPPON SHOKUBAI INDONESIA Jl. Raya Anyer km. 122, Ciwandan Cilegon 42447 Banten 62-254-600660 (Hunting) 62-254-600657 62-254-600660 (Hunting)



2. HAZARD IDENTIFICATION GHS CLASSIFICATION Flammable Liquid Acute Toxicity Oral Dermal Inhalation (vapor) Skin Corrosion/Irritation Serious Eye Damage /Eye Irritation Specific Target Organs/Systemic Toxicity (Single Exposure) Specific Target Organs/Systemic Toxicity (Repeated Exposure) Hazardous To Aquatic Environment - Acute Hazard



: Category 3 : Category 3 : Category 3 : Category 3 : Category 1A : Category 1 : Category 1 (Respiratory organs) Category 2 (liver) : Category 1 (Respiratory organs) : Category 1



GHS LABEL ELEMENT DANGER



PT. NIPPON SHOKUBAI INDONESIA KAWASAN INDUSTRI PANCAPURI JL. RAYA ANYER KM 122 CIWANDAN, CILEGON 42447 BANTEN, INDONESIA TEL :(62-254)600660 (HUNTING), FAX :(62-254)600657, 600658



M S D S No. 002 – NSI – 1998 (SDS-Acrylic Acid)



Page 2 of 9



HAZARD STATEMENTS Physical and chemical hazards :  Flammable liquid and vapor. Human Health effects:  Toxic if swallowed.  Toxic in contact with skin.  Toxic if inhaled (Vapor).  Causes severe skin burns and eye damage.  Causes serious eye damage.  Cause damage to organs (respiratory system).  May cause damage to organs (liver).  Cause damage to respiratory through prolonged or repeated exposure (respiratory system). Environmental Effects:  Very toxic to aquatic life. Other Information:  Polymerization with explosive violence.  This substance is biodegradable.  This substance is not bioaccumulative. PRECAUTIONARY STATEMENTS  Use only outdoors or in a well-ventilated area.  Wear respiratory protection, protective glove/clothing/face protection as specified by manufacturer/supplier or the competent authority.  Keep container tightly closed.  Keep away from ignition sources such as sparks/open flames/hot surface—No Smoking.  Use only non sparking tools.  Take precautionary measures against static discharge.  Prevent build-up of electrostatic charges.  Do not breathe vapor/spray.  Wash hand thoroughly after handling.  Do not eat, drink or smoke when using this product  Avoid breathing dust/fume/gas/mist/vapors/spray  Avoid release to the environment. 3. COMPOSITION / INFORMATION ON INGREDIENTS      



SUBSTANCE/MIXTURED CHEMICAL NAME SYNONYMS CAS REGISTRY NUMBER CONCENTRATION RANGE CHEMICAL FORMULA



: : : : : :



Substance Acrylic Acid 2-Propenoic acid 79-10-7 99.7 % CH 2 =CHCOOH



4. FIRST-AID MEASURES 



INHALATION : Remove to fresh air. If not breathing, give artificial respiration. If breathing difficult, give oxygen. Get immediate medical attention.



PT. NIPPON SHOKUBAI INDONESIA KAWASAN INDUSTRI PANCAPURI JL. RAYA ANYER KM 122 CIWANDAN, CILEGON 42447 BANTEN, INDONESIA TEL :(62-254)600660 (HUNTING), FAX :(62-254)600657, 600658



M S D S No. 002 – NSI – 1998 (SDS-Acrylic Acid)   



Page 3 of 9



SKIN CONTACT : Immediately flush skin with plenty of water. Remove clothing. Get immediate medical attention. EYE CONTACT : Immediately flush eyes with plenty of water for at least 15 minutes. Get immediate medical attention. INGESTION : If swallowed, do not induce vomiting. Give victim one or two glasses of milk or water. Call a physician immediately. Never give anything by mouth to an unconscious person.



5. FIRE-FIGTHING MEASURES  







SUITABLE EXTINGUISH MEDIA : Use powder, alcohol-resistant foam, carbon dioxide, a large amount of water SPECIFIC METHODS OF FIRE-FIGTHING : Shut off fuel to fire if possible to do so without hazard. Apply water from a safe distance to cool and protect surrounding area. Keep personnel removed from and upwind of fire. SPECIAL EQUIPMENT FOR THE PROTECTION OF FIREFIGHTERS : As in any fire, wear self-contained breathing apparatus with full face peace operated in positive pressure mode and full protective gear.



6. ACCIDENTAL RELEASE MEASURES 











PERSONAL PRECAUTION : Evacuate personnel from the lee. Evacuate non essential personnel. Shut off all sources of ignition; No flares, smoking, or flames in the area. Wear proper protective equipment. . ENVIRONMENTAL PRECAUTION : Do not pour into natural waterway or public drainage system. Because odor is strong, you manage appropriately such that you inform the fact to the resident that leakage occurred. METHODS FOR CLEANING UP : Remove the spilt liquid using appropriate absorbent such as sand, sawdust, or rags. According to the situation, use caustic soda of 5 to 10 % for neutralization. Then wash with plenty of water and treat the washing as waste water. Low concentration waste water from Acrylic Acid is treated by activated sludge process.



7. HANDLING AND STORAGE  HANDLING :  Appropriate technical measure : Wash thoroughly after handling. Avoid contact with eyes, skin and clothing. Use only in a well-ventilated area. Do not breathe vapor. Prevent build-up of electrostatic charges. 



Precautions for safe handling of the chemical product. Don’t leak, overflow, and scatter. Minimize vapor generation and accumulation. Shut off all source of ignition; no flares, smoking or flames in the area. Avoid falling, dropping, shocking and dragging a container.



PT. NIPPON SHOKUBAI INDONESIA KAWASAN INDUSTRI PANCAPURI JL. RAYA ANYER KM 122 CIWANDAN, CILEGON 42447 BANTEN, INDONESIA TEL :(62-254)600660 (HUNTING), FAX :(62-254)600657, 600658



M S D S No. 002 – NSI – 1998 (SDS-Acrylic Acid) 



Page 4 of 9



STORAGE :  Suitable storage conditions : When it stores in a tank, keep the liquid temperature from 15 to 25 oC and the gas phase concentration of oxygen from 7 to 21 vol%. (in the presence of oxygen under 7 vol%. polymerization may occur.) The electrical apparatus makes explosion-proof construction. The tank and apparatus are grounded. When product solidifies, a portion little inhibitor is formed. If product is melt at high temperature, container may rupture or explode. Melt only in the water bath under 40 oC. After the contents are completely melted, the liquid should be well mixed to distribute inhibitor. Do not store in direct sunlight. Keep in the well-ventilated areas. Keep away from heat and flame.  Safe packaging materials : Because of corrosiveness It keeps in the stainless steel or polyethylene container.



8. EXPOSURE CONTROL/PERSONAL PROTECTION 



ENGINEERING MEASURES : Facilities storing or utilizing this substance should be equipped with an eyewash facility and a safety shower. Use process enclosures, local exhaust ventilation, or others engineering controls.







CONTROL PARAMETERS



:



CHEMICAL NAME



CAS RN



ACGIH (2006)



OSHA (2006)



100% (by wt)



Acrylic Acid



79-10-7



TWA 2 ppm (Skin)



Not established



99.7 %







PERSONAL PROTECTIVE EQUIPMENT : RESPIRATORY PROTECTION : Chemical cartridge respirator for an organic vapor, or pressure self-contained breathing apparatus. HAND PROTECTION : Chemical resistant gloves. EYE PROTECTION : Wear safety glasses with side shields or goggles and a face shield. SKIN, AND BODY PROTECTION : Suitable safety clothes and shoes. 9. PHYSICAL AND CHEMICAL PROPERTIES        



Form Color Odor pH Boiling Points Melting Point Flash Point Auto ignition Temperature



: Liquid : Colorless : Strong irritating odor : 2.3 (20oC 1 mol/l aqueous solution)1) : 141 oC 2) : 13.5 oC 2) : 51.4 oC (closed cup)2) : 428 oC 2)



PT. NIPPON SHOKUBAI INDONESIA KAWASAN INDUSTRI PANCAPURI JL. RAYA ANYER KM 122 CIWANDAN, CILEGON 42447 BANTEN, INDONESIA TEL :(62-254)600660 (HUNTING), FAX :(62-254)600657, 600658



M S D S No. 002 – NSI – 1998 (SDS-Acrylic Acid) 



Explosion Properties



     



Vapor Pressure Vapor Density Density/Specific Gravity Solubility in Water Octanol /Water Partition Coefficient Other Data



Page 5 of 9



: Lower explosion limit 2 vol% 2) Upper explosion limit 17 vol% 2) : 400 Pa (20oC)2) : 2.49 2) : 1.05 (d 20 20) 2) : Very good 2) : LogP 0/W 0.46 (25oC) 4) : Heat of Combustion : 19008 kJ/kg 2)



10. STABILITY AND REACTIVITY :    



STABILITY : Substance may undergo hazardous polymerization if stored at temperature above 30oC or in the presence of oxygen under 7 vol%. POSSIBLE HAZARDOUS REACTIONS : Hazardous polymerization may occur if contaminated with strong oxidizing agents, alkaline substances or acids. CONDITIONS TO AVOID : Heating. Flame. Spark. Contact with strong oxide or peroxide. MATERIALS TO AVOID : Strong oxide. Peroxide.



11. TOXICOLOGICAL INFORMATION 



ACUTE TOXICITY oral



inhalation



dermal







 



LOCAL EFFECT Irritation: skin eye



: rat rat mouse rabbit



LD 50 LD 50 LD 50 LD 50



140-1400 mg/kg 340 mg/kg 830 mg/kg 250 mg/kg



rat rat



LC 50 LC 50



>5.12 mg/l/4H 4) 3600 mg/m3



rabbit rabbit



LD 50 LD 50



300-640 mg/kg 290 mg/kg



rabbit rabbit



highly corrosive Severe Irritant



SENSITIZATION : Skin sensitizing in guinea pig not sensitizing CRONIC TOXICITY OR LONG TERM TOXICITY Sub-Chronic Toxicity : - Repeated dose toxicity (90 days) oral (90 days) rat NOAEL inhalation (90 days)



.



4) 2) 4) 4)



2)



2) 2)



4) 4)



4)



:



40 mg/kg (male) 83 mg/kg (female) rat NOAEC 25 ppm (0.07 mg/l) mouse NOAEC 5 ppm (0.015 mg/l) mouse LOAEC(local) 5 ppm (0.015 mg/l)



4) 4) 4) 4) 4)



PT. NIPPON SHOKUBAI INDONESIA KAWASAN INDUSTRI PANCAPURI JL. RAYA ANYER KM 122 CIWANDAN, CILEGON 42447 BANTEN, INDONESIA TEL :(62-254)600660 (HUNTING), FAX :(62-254)600657, 600658



M S D S No. 002 – NSI – 1998 (SDS-Acrylic Acid)



Page 6 of 9



- No cases have been reported on the toxicological information of human beings caused by repeated exposure to low concentration vapors of acrylic acid. 2) - In test on rats and mice in which acrylic acid (13 weeks) were administered via inhalation exposures, local irritation centered on the upper part of respiratory tract was observed. Moreover, administration of acrylic acid causes generalized intoxication and irritation in gastrointestinal tracts (forestomach and esophagus). 2) Chronic Toxicity 



CARCINOGENICITY : CHEMICAL NAME



CAS RN



IARC



ACGIH



NTP



EU



OSHA



Acrylic Acid



79-10-7



3



A4



Not established



Not established



Not established



Oral Dermal 



: No relevant information found



rat rat



no treatment related tumors 4) no treatment related tumors 4)



MUTAGENICITY EFFECT : [In vitro] Ames test. Chromosomal aberration Gene mutation (CHO cells) UDS test CHO/HGPRT L5178Y lymphoma cell TK DNA lesion, Irregular DNA synthesis DNA addition Genetic transformation [In vivo] Chromosomal aberrations assay : Dominant lethal assay : Sex-linked recessive lethal : DNA addition : Dominant lethal : Conclusion for human







:



TERATOGENICITY EFFECT: Oral rat NOAEL rat rat Inhalation rat NOAEC rabbit NOAEC rat



negative 4) positive 4) negative 4) negative 4) negative 2) positive 2) positive 2) positive 2) negative 2) rat mouse drosophila rat mouse



negative negative negative negative negative



4) 4) 2) 2) 2)



negative 4) 53mg/kg (foetal data) 4) 750 ppm negative 2) 5000 ppm in drinking water negative 2) 360 ppm (1.06 mg/l) (foetal data) 4) 225 ppm (0.67mg/l) (foetal data) 4) 300 ppm (negative) 2)



PT. NIPPON SHOKUBAI INDONESIA KAWASAN INDUSTRI PANCAPURI JL. RAYA ANYER KM 122 CIWANDAN, CILEGON 42447 BANTEN, INDONESIA TEL :(62-254)600660 (HUNTING), FAX :(62-254)600657, 600658



M S D S No. 002 – NSI – 1998 (SDS-Acrylic Acid) 



Page 7 of 9



REPRODUCTION TOXICITY: Oral rat NOAEL 240 mg/kg (General toxicity) 4) NOAEL 460 mg/kg (Repro. Tox. Parental) 4) NOAEL 53 mg/kg (Repro. Tox. F1 generation) 4) Inhalation rat 360 ppm negative 2) rabbit 225 ppm negative 2) No effects on reproduction in dams were observed up to a highest dose of 5000 ppm of acrylic acid in chronic drinking water studies for 2 generations. 2)



12. ECOLOGICAL INFORMATION  



 



MOBILITY



: Considering its physical and chemical property, there is a possibility of moving to soil. PERSISTENCE/DEGRADABILITY : TOD : 1.33 2) BOD 5 : 1.1 (exposed for 5 days) 2) COD : 1.33 2) Biodegradability : Biodegradable 4) BIOACCUMULATION : This substance not bioaccumulative 2) ECOTOXICITY Fish Toxicity : Oncorhynchus mykiss LC 50 96H 27 mg/l 4) Golden orfe LC 50 48H 315 mg/l 2) Oryzas latipies (himedaka) LC 50 48H 80 mg/l 2) Rainbow trout LC 50 96H 27 mg/l 2) Carp LC 50 24H 100 mg/l 2) Other data : Daphnids Dapnids Daphnia Daphnia Algae Green algae Green algae Blue algae Sediment



EC 50 NOEC NOEC NOEC EC 50 EC 50 EC 10 LC 50 EC 50 LC 50 NOEC



48H 21Days 21Days 21Days 48H 72H 72H 8 Days 96 H 8 Days 28Days



47 mg/l 4) 7 mg/l 4) 7 mg/l (maternal toxicity) 4) 12 mg/l (reproduction) 4) 95 mg/l 2) 0.13 mg/l 4) 0.03 mg/l 4) 18 mg/l 2) 0.17mg/l 2) 0.15mg/l 2) 100 mg/l 4)



13. DISPOSAL CONSIDERATION 



Waste from residues : Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is flammable. Do not flush into the sewer.







Any contaminated packaging : Empty drums should be completely drained, properly bunged and promptly returned to a drum reconditioner, or properly disposed of. Comply with all federal, state and local regulation. Do not dump this product into sewer, on the ground or into any body of water.



 



PT. NIPPON SHOKUBAI INDONESIA KAWASAN INDUSTRI PANCAPURI JL. RAYA ANYER KM 122 CIWANDAN, CILEGON 42447 BANTEN, INDONESIA TEL :(62-254)600660 (HUNTING), FAX :(62-254)600657, 600658



M S D S No. 002 – NSI – 1998 (SDS-Acrylic Acid)



Page 8 of 9



14. TRANSPORT INFORMATION 



The UN classification number [IMDG] Proper shipping name : Acrylic Acid, stabilized UN class : 8 (corrosive substance) UN number : 2218 Packing group : II







Specific precautionary transport measures and condition : Avoid falling, dropping, shocking and dragging a container. Protect a container from direct sunlight. Secure the grounding of the vehicle to avoid static electrification before starting the liquid transfer. After discharging the product from a tank lorry, the remnant liquid in piping must be completely eliminated.







Any transportation practice must be in compliance with laws and regulation in your country or region.



15. REGULATORY INFORMATION 







US STATUS : TSCA Inventory SARA TITLE III 313



: Listed : Listed



EU STATUS : EINECS : Listed (No.201-177-9) Classification & labeling (67/548/EEC) : [CLASSIFICATION] R10 Xn ; R20/21/22 C; R35 N; R50 [LABELING] [C;N] R10 - Flammable R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed. R35 - Cause severe burns. R50 - Very toxic to aquatic organisms. S1/S2 - Keep locked up and out of the reach of children. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 - Wear suitable protective clothing, gloves and eye/face Protection. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S61 - Avoid release to the environment. Refer to special instructions/ Safety Data Sheet.



PT. NIPPON SHOKUBAI INDONESIA KAWASAN INDUSTRI PANCAPURI JL. RAYA ANYER KM 122 CIWANDAN, CILEGON 42447 BANTEN, INDONESIA TEL :(62-254)600660 (HUNTING), FAX :(62-254)600657, 600658



M S D S No. 002 – NSI – 1998 (SDS-Acrylic Acid)



Page 9 of 9







Registration STATUS in the lists of existing chemicals of various countries Canada (CEPA) : Listed in DSL Japan (ENCS) : (2)-984 Australia (AICS) : Listed Korea (ECL) : KE-29442 Switzerland (SWISS) : G-2118 Philippine (PICCS) : Listed China (SEPA) : Listed







Regulatory information with regard to this substance in your country or region should be examined by your own responsibility.



16. OTHER INFORMATION 



REFERENCES : 1) Data generated by NIPPON SHOKUBAI CO.,LTD. 2) Safety Guidebook for Handling of Acrylic Acid and Acrylic Esters 7th edition. (May, 2007) Japanese Acrylic Ester Manufactures (JAEM). 3) Ministry International Trade & Industry Official Bulletin. (27.Aug. 1975) 4) OECD/HPV (SIAM 13, 6-9 Nov. 2001)







To the best of our knowledge, the information contained here in is accurate. However, neither PT. NIPPON SHOKUBAI INDONESIA nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist.