Sds Rewocid WK 30 PDF [PDF]

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First compiled date: 2020.02.03 Revision Date: 2020.02.03 Version #: 1.0 Product name: REWOCID WK 30 Amphoteric surfactant in aqueous solution, biocidal active in aqueous solution



CHEMICAL PRODUCT SAFETY DATA SHEET Prepared in accordance with GB/T 16483 and GB/T 17519.



1. Identification of the substance or mixture and of the supplier Product name: REWOCID WK 30



Chemical name: Amphoteric surfactant in aqueous solution, biocidal active in aqueous solution Recommended use and restriction on use Recommended use: Industrial use Restrictions on use: None known. Manufacturer/Importer/Supplier/Distributor Information Company Name



: Evonik Operations GmbH Rellinghauser Str. 1-11 45128 Essen Germany



Telephone



: +49 201 173 01 +86 21 6119 1586



E-mail



: [email protected]



Emergency telephone number: 24-Hour Health Emergency



: +86 532 8388 9090 (China 24h)



Issue Date:



2020.02.03



Version #:



1.0



Revision Date:



2020.02.03



First compiled date:



2020.02.03



2. Hazard(s) identification Emergency Overview: Yellow liquid. Odor: Characteristic. Corrosive to metal Harmful in contact with skin. Causes severe skin burns and eye damage. Causes serious eye damage. Harmful if swallowed. May cause damage to organs through prolonged or repeated exposure. Very toxic to aquatic life. Toxic to aquatic life with long lasting effects. Notes to physician: Treat symptomatically. None known.



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First compiled date: 2020.02.03 Revision Date: 2020.02.03 Version #: 1.0 Product name: REWOCID WK 30 Amphoteric surfactant in aqueous solution, biocidal active in aqueous solution



GHS classification Physical Hazards Corrosive to metal



Category 1



Health Hazards Specific Target Organ Toxicity Repeated Exposure Acute toxicity (Oral) Acute toxicity (Dermal) Skin Corrosion/Irritation Serious Eye Damage/Eye Irritation Specific Target Organ Toxicity Repeated Exposure



Category 21. Category 4 Category 4 Category 1A Category 1 Category 2



Target Organs 1. Systemic toxicity Environmental Hazards Acute hazards to the aquatic environment



Chronic hazards to the aquatic environment Label Elements Pictograms:



Category 1



Category 2



Signal Word:



Danger



Hazard Statement:



May be corrosive to metals. Harmful if swallowed. Harmful in contact with skin. Causes severe skin burns and eye damage. Causes serious eye damage. May cause damage to organs through prolonged or repeated exposure. Very toxic to aquatic life. Toxic to aquatic life with long lasting effects.



Precautionary Statements



Prevention:



Keep only in original packaging. Do not breathe dust/fume/gas/mist/vapors/spray. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Avoid release to the 2/14



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First compiled date: 2020.02.03 Revision Date: 2020.02.03 Version #: 1.0 Product name: REWOCID WK 30 Amphoteric surfactant in aqueous solution, biocidal active in aqueous solution



environment. Wear protective gloves/protective clothing/eye protection/face protection. Response:



IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Call a POISON CENTER/doctor if you feel unwell. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. Wash contaminated clothing before reuse. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention if you feel unwell. Absorb spillage to prevent material damage.



Storage:



Store locked up. Store in a corrosion-resistant container with a resistant inner liner.



Disposal:



Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.



Physical and Chemical Hazards: Corrosive to metal Health Hazards: Harmful in contact with skin. Causes severe skin burns and eye damage. Causes serious eye damage. Harmful if swallowed. May cause damage to organs through prolonged or repeated exposure. Possible routes of entry: Eyes, Skin, Inhalation, Ingestion Environmental Hazards: Very toxic to aquatic life. Other hazards which do not result in GHS classification:



None known.



3. Composition/information on ingredients Chemical name: Amphoteric surfactant in aqueous solution, biocidal active in aqueous solution Mixtures Chemical Identity



CAS number



Content in percent (%)*



Amines, N-C10-16alkyltrimethylenedi-, reaction products with chloroacetic acid



139734-65-9



>=20 - =1 - 480 min Glove thickness: 1 mm Material: gloves made of natural latex Break-through time: > 480 min Glove thickness: 0.5 mm Material: gloves made of chloroprene (CR, e.g. Neoprene) Break-through time: > 480 min Glove thickness: 0.65 mm Material: gloves made of nitril (NBR) Break-through time: > 480 min Glove thickness: 0.4 mm Material: gloves made of butyl (IIR) Break-through time: > 480 min Glove thickness: 0.3 mm Material: protective gloves made of fluorinated rubber (FKM, e.g. Viton) Break-through time: > 480 min Glove thickness: 0.7 mm



Skin and Body Protection:



suitable protective clothing recommended



Respiratory Protection:



in case of formation of vapours/aerosols: Short term: filter apparatus, combination filter A-P2



Hygiene measures:



Do not eat, drink or smoke when working. Wash hands before breaks and immediately after handling the product. Do not wear contaminated clothing.



9. Physical and chemical properties Appearance Physical state: Form: Color: Odor: Odor Threshold: pH: Freezing point: Boiling Point: Flash Point: Evaporation Rate: Flammability (solid, gas): Explosive limit - upper (%): Explosive limit - lower (%): Vapor pressure: Vapor density (air=1):



liquid liquid Yellow Characteristic No data available. 7.8 - 8.2 < 0 °C 100 °C > 150 °C (DIN EN 22719) No data available. No data available. No data available. No data available. Not applicable No data available. 6/14



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First compiled date: 2020.02.03 Revision Date: 2020.02.03 Version #: 1.0 Product name: REWOCID WK 30 Amphoteric surfactant in aqueous solution, biocidal active in aqueous solution



Density: Relative density: Solubility in Water: Solubility (other): Partition coefficient (n-octanol/water): Self Ignition Temperature: Decomposition Temperature: Kinematic viscosity: Dynamic viscosity:



0.995 - 1.005 g/cm3 (20 °C) (OECD 109) No data available. Soluble Soluble No data available. not to be expected, given the composition employed Stable under normal conditions. No data available. 50 - 150 mPa.s (20 °C)



Other information Explosive properties: Oxidizing properties: Minimum ignition temperature: Formation of Flammable Gases: Metal Corrosion:



Not to be expected in view of the structure Not to be expected in view of the structure Not determined. Not to be expected in view of the structure Corrosive to metal



10. Stability and reactivity Reactivity:



see section "Possibility of hazardous reactions"



Chemical Stability:



The product is stable under normal conditions.



Possibility of hazardous reactions:



No hazardous reactions with proper storage and handling.



Conditions to avoid:



None with proper storage and handling.



Incompatible Materials:



Unknown



Hazardous Decomposition Products:



None with proper storage and handling.



11. Toxicological information Information on likely routes of exposure Inhalation: If handled correctly, not a relevant route of exposure. Information on effects are given below. Skin Contact:



Relevant route of exposure. Information on effects are given below.



Eye contact:



Relevant route of exposure. Information on effects are given below.



Ingestion:



If handled correctly, not a relevant route of exposure. Information on effects are given below.



Symptoms related to the physical, chemical and toxicological characteristics Inhalation:



No data available.



Skin Contact:



No data available. 7/14



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First compiled date: 2020.02.03 Revision Date: 2020.02.03 Version #: 1.0 Product name: REWOCID WK 30 Amphoteric surfactant in aqueous solution, biocidal active in aqueous solution



Eye contact:



No data available.



Ingestion:



No data available.



Information on toxicological effects Acute toxicity (list all possible routes of exposure) Oral Product:



Dermal Product:



Inhalation Product:



Repeated dose toxicity Product:



Skin Corrosion/Irritation Product:



Acute toxicity estimate: > 5,000 mg/kg (Calculation method) LD 50 (Rat, male/female): > 660 mg/kg (EC Directive 92/69/EEC B.1 Acute Toxicity (Oral), No )



ATEmix 1,333.33 mg/kg



No data due to skin-corrosive actionNot classified for acute toxicity based on available data.No data available.



No observed adverse effect level (Mouse, Oral, 78 Weeks, daily): 2 mg/kg bw/day related to 100% active substance No observed adverse effect level (Rat, pharyngal probe, daily): 2.5 mg/kg bw/day related to 100% active substance No observed adverse effect level (Beagle, pharyngal probe, daily): 5 mg/kg bw/day related to 100% active substance



Corrosive OECD 404 Rabbit, 4 h: Corrosive Irritating. OECD 404 Rabbit, 4 h: Irritating. Tested as 20 % solution



Serious Eye Damage/Eye Irritation Product: Corrosive Rabbit: Corrosive Tested as 20 % solution



Respiratory or Skin Sensitization Product: Magnussona i Kligmana., OECD 406 (Guinea Pig): not sensitizing



Carcinogenicity Product:



No data available. 8/14



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First compiled date: 2020.02.03 Revision Date: 2020.02.03 Version #: 1.0 Product name: REWOCID WK 30 Amphoteric surfactant in aqueous solution, biocidal active in aqueous solution



Germ Cell Mutagenicity In vitro Product:



In vivo Product:



Reproductive toxicity Product:



Ames test (OECD 471): negative Chromosomal aberration (OECD 473): negative HGPRT-Test (OECD 476): negative



No data available.



No data available.



Specific Target Organ Toxicity - Single Exposure Product: Not classified Specific Target Organ Toxicity - Repeated Exposure Product: May cause damage to organs through prolonged or repeated exposure. Target Organs Specific Target Organ Toxicity - Repeated Exposure: Systemic toxicity Aspiration Hazard Product:



Other effects:



No evidence of aspiration toxicity



No data available.



12. Ecological information Ecotoxicity: Acute hazards to the aquatic environment: Fish Product:



LC 50 (Oncorhynchus mykiss, 96 h): 207.4 µg/l



Aquatic Invertebrates Product:



EC 50 (Daphnia magna, 48 h): 0.0333 mg/l



Chronic hazards to the aquatic environment: Fish Product:



NOEC (Oncorhynchus mykiss, 28 d): >= 0.0523 mg/l



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First compiled date: 2020.02.03 Revision Date: 2020.02.03 Version #: 1.0 Product name: REWOCID WK 30 Amphoteric surfactant in aqueous solution, biocidal active in aqueous solution



Aquatic Invertebrates Product:



Toxicity to Aquatic Plants Product:



NOEC (Daphnia magna, 21 day): 2.4 µg/l NOEC (Daphnia magna, 21 day): 2.4 µg/l



ErC50 (Algae (Pseudokirchneriella subcapitata), 72 h): 0.0237 mg/l NOEC (Algae (Pseudokirchneriella subcapitata), 72 h): 0.00955 mg/l



Persistence and Degradability Biodegradation Product:



BOD/COD Ratio Product:



94 % (28 d, OECD 301 A) 0 % (60 d, OECD 311)



No data available.



Bioaccumulative potential Bioconcentration Factor (BCF) Product: No significant bioaccumulation.



Partition Coefficient n-octanol / water (log Kow) Product: Log Kow: No data available.



Mobility in soil:



No data available.



Other adverse effects:



Do not allow to enter soil, waterways or waste water canal. The product is classified as highly hazardous to waters (according to the German Regulation on the Classification of Substances Hazardous to Waters (WwSV).



13. Disposal considerations Disposal methods:



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It should not be released into the environment. Do not dump into any sewers, on the ground, or into any body of water. Please follow local and national laws and regulations, and regulations may vary from region to region. The identification and subsequent compliance of chemical waste is the main responsibility of the waste generator, waste product listed in National Hazardous Wastes Catalogue must be entrusted to an qualified waste disposal agency for disposal. Chemical waste generators must determine whether the waste chemical is classified as general waste or hazardous waste. As a supplier of chemical products, it is impossible to know the specific use, manufacture process and process sources of the waste from downstream user, so it is impossible to provide information on the waste code after the product is discarded. 10/14



First compiled date: 2020.02.03 Revision Date: 2020.02.03 Version #: 1.0 Product name: REWOCID WK 30 Amphoteric surfactant in aqueous solution, biocidal active in aqueous solution



Contaminated Packaging:



Uncontaminated packaging can be recycled and reused. Contaminated packaging should be disposed of as for product, to be entrusted to an qualified waste disposal agency for recycling or disposal. Please follow local and national laws and regulations, and regulations may vary from region to region. Can not be treated as domestic waste.



14. Transport information Domestic regulation Road transport (GB 6944/12268) UN number Proper shipping name



: :



Class Packing group Labels



: : :



UN 1760 CORROSIVE LIQUID, N.O.S. (reaction products of propane diamine, alkyl derivates and chloroacetic acid) 8 II 8



International Regulations IATA-DGR UN/ID No. Proper shipping name



: : : :



UN 1760 Corrosive liquid, n.o.s. (reaction products of propane diamine, alkyl derivates and chloroacetic acid) 8 II 8 855



:



851



:



yes



IMDG-Code UN number Proper shipping name



: :



Class Packing group Labels EmS Code Marine pollutant Remarks



: : : : : :



UN 1760 CORROSIVE LIQUID, N.O.S. (reaction products of propane diamine, alkyl derivates and chloroacetic acid) 8 II 8 F-A, S-B yes Stowage category B - Clear of living quarters, "Separated from" acids - Seg.Grp.: Alkalis, IMDG Code segregation group 18 - Alkalis



Class Packing group Labels Packing instruction (cargo aircraft) Packing instruction (passenger aircraft) Environmentally hazardous



: :



Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied.



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First compiled date: 2020.02.03 Revision Date: 2020.02.03 Version #: 1.0 Product name: REWOCID WK 30 Amphoteric surfactant in aqueous solution, biocidal active in aqueous solution



Special precautions for user The transport classification(s) provided herein are for informational purposes only, and solely based upon the properties of the unpackaged material as it is described within this Safety Data Sheet. Transportation classifications may vary by mode of transportation, package sizes, and variations in regional or country regulations.



15. Regulatory information China. Catalog of Hazardous Chemicals (2015 Edition) Regulated China. Precursor Chemicals (Decree No. 445 of the PRC on Regulation for Administration of Precursor Chemicals, Appendix: Categories 1-3) Not Regulated



China. Explosive Precursor Hazardous Chemicals (2017) Not Regulated China. Catalog of First Batch Hazardous Chemicals Subject to Key Supervision (2011) Not Regulated China. Catalog of Second Batch Hazardous Chemicals Subject to Key Supervision (2013) Not Regulated The following laws, regulations, rules and standards include provisions governing the management of chemicals: Regulations on Safety Administration of Hazardous Chemicals (Decree No.591 of the State Council) Occupational Exposure Limits for Hazardous Agents in the Workplace, Part 1, Chemical Hazardous Agents (GBZ 2.1) List of Dangerous Goods (GB 12268) Classification and Code of Dangerous Goods (GB 6944) Safety Data Sheet for Chemical Products - Content and Order of Sections (GB/ T 16483) Guidance on the Compilation of Safety Data Sheets for Chemical Products (GB/ T 17519) General Rules for Preparation of Precautionary Label for Industrial Chemicals (GB 15258) National Hazardous Wastes Catalogue



Inventory Status: China Inv. Existing Chemical Substances:



Included on Inventory.



Should comply with local regulations in respect of this product.



16. Other Information 12/14 CN



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First compiled date: 2020.02.03 Revision Date: 2020.02.03 Version #: 1.0 Product name: REWOCID WK 30 Amphoteric surfactant in aqueous solution, biocidal active in aqueous solution



First compiled date:



2020.02.03



Issue Date:



2020.02.03



Version #:



1.0



Revision Date:



2020.02.03



Abbreviations and acronyms ASTM: American Society for Testing and Materials ATP: Adaptation to Technical Progress BCF: Bioconcentration factor BOD: Biochemical oxygen demand c.c.: closed cup CAS: Chemical Abstract Services CESIO: European Committee of Organic Surfactants and their Intermediates CMR: carcinogenic-mutagenic-toxic for reproduction COD: Chemical oxygen demand DIN: German Institute for Standardization EC50: half maximal effective concentration GHS: Globally Harmonized System of Classification and Labelling of Chemicals (GHS) GLP: Good Laboratory Practice GMO: Genetic Modified Organism IARC: International Agency for Research on Cancer IATA: International Air Transport Association ICAO: International Civil Aviation Organization IMDG: International Maritime Dangerous Goods ISO: International Organization For Standardization LC50: 50 % Lethal Concentration LD50: 50 % Lethal Dose L(E)C50: LC50 or EC50 LOAEL: Lowest observed adverse effect level LOEL: Lowest observed effect level MAC: Maximum allowable concentration NOAEL: No observed adverse effect level NOEC: no observed effect concentration NOEL: no observed effect level o. c.: open cup OECD: Organisation for Economic Cooperation and Development OEL: Occupational Exposure Limit PC-TWA: Permissible concentration - time weighted average PC-STEL: Permissible concentration - short term exposure limit PEC: Predicted effect concentration PNEC: Predicted no effect concentration REACH: REACH registration RID: Convention concerning International Carriage by Rail STOT: Specific Target Organ Toxicity TA: Technical Instructions TPR: Third Party Representative (Art. 4) VOC: volatile organic compounds WHO: World Health Organization



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First compiled date: 2020.02.03 Revision Date: 2020.02.03 Version #: 1.0 Product name: REWOCID WK 30 Amphoteric surfactant in aqueous solution, biocidal active in aqueous solution



Training information:



Comply with national laws regulating employee instruction.



Further Information:



No data available.



References: relevant manuals and publications own examinations own toxicological and ecotoxicological studies toxicological and ecotoxicological studies of other manufacturers SIAR OECD-SIDS RTK public files Chinese regulations and inventories



Revision Information



Changes since the last version are highlighted in the margin. This version replaces all previous versions.



Disclaimer:



This information and all further technical advice is based on our present knowledge and experience. However, it implies no liability or other legal responsibility on our part, including with regard to existing third party intellectual property rights, especially patent rights. In particular, no warranty, whether express or implied, or guarantee of product properties in the legal sense is intended or implied. We reserve the right to make any changes according to technological progress or further developments. The customer is not released from the obligation to conduct careful inspection and testing of incoming goods. Performance of the product described herein should be verified by testing, which should be carried out only by qualified experts in the sole responsibility of a customer. Reference to trade names used by other companies is neither a recommendation, nor does it imply that similar products could not be used.



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