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Nilai Anda
Nama
AZAS TEKNIK KIMIA I TOPIK : NERACA MASSA DENGAN REAKSI (SINGLE REACTION DAN COMBUSTION REACTION)
PROBLEM 1. SUB-TOTAL 100 Methanol is dehydrogenated in a catalytic reactor to form formaldehyde in the reaction: CH3OH → HCHO + H2 Formaldehyde in the reactor product is separated from the unreacted methanol and hydrogen. The production rate of formaldehyde is 30 kmol. If the conversion is 60%, calculate the required feed rate of methanol to the process in kmol. Solution : production rate of HCHO = fractional conversion = Component
30
kmol
0.60
F mol fract.
CH3OH HCHO H2 Total
mol 1 0 0 1
50 0 0 50
REACTION P1 coef. mol mol fract. -1 -30 0 1 30 1 1 30 0 30 1
mol 0 30 0 30
PROBLEM 2. SUB-TOTAL 0 The molar feed rate to a continuous ammonia synthesis reactor is 100 mol/min nitrogen, 150 mol/min hydrogen. The ammonia formation reaction is N2 +3H2 → 2NH3 The percent conversion of the limiting reactant in the reactor is 60.0%. Determine the molar flow rate of limiting reactant in the reactor effluent stream?
Solution : F Component mol fract. N2 H2 NH3 Total
REACTION mol (mol/min)
coef.
P
mol (mol/min) mol fract. mol (mol/min)
PROBLEM 3. SUB-TOTAL 0 Butane is completely burned in a process fed with 25.0% excess air. Based on 1 mol/h of butane, determine the composition in mole fractions of oxygen in product stream. Solution : Basis : Component
mole of butane = B mole fract.
mol
mol/h
A mole fract.
mol
REACTION coef. mol
C4H10 O2 N2 CO2 H2O Total
PROBLEM 4. SUB-TOTAL 0 One hundred mol/h of butane and 5000 mol/h of air are fed into a combustion reactor. Calculate the percent excess The combustion reaction: 2C4H10 + 13O2 → 8CO2 + 10H2O
Solution : Basis :
Component C4H10 O2 N2 CO2 H2O Total
mole of butane =
G mole fract.
mol
mol/h
A mole fract.
mol
REACTION coef. mol
Nama
NIM
N)
tion:
d hydrogen. The equired feed rate of
P2 mol fract. 0.4 0 0.6 1
mol 20 0 30 50
Answer : Feed rate of methanol =
50
kmol
ogen, 150 mol/min
he molar flow rate of
Answer : flow rate of limiting reactant in the reactor effluent stream =
mol/min
n in product stream.
P mole fract.
mol
Answer : composition of O2 in product =
tor. Calculate the percent excess air.
P mole fract.
mol
Answer : the percent excess air =